降阶扩展卡尔曼滤波算法在船用INS/GPS组合导航系统中的应用

TNNS(真航向导航系统)由MS860接收机、INS及处理数据的PC/104架构的嵌入式工控机构成。针对TNNS推导了INS(惯性导航系统)的误差模型,提出了适合于TNNS的降阶扩展卡尔曼滤波算法组合GPS和INS。系统在东海作了三次海试,软件及滤波算法平台由C/C 编制。海上试验表明,组合滤波后,INS的位置误差由100m降低到40m以下;进行最优化滤波后的航向误差σ由原来的0.105°减小为0.034°,纵横摇的误差也大幅减小。整个海试结果表明,在TNNS中组合GPS/INS采用的降阶扩展卡尔曼滤波算法,大幅提高了系统精度和可靠性。     

Ragged oscillation death in coupled nonidentical oscillators

In this paper, the effect of spatial frequencies distributions on the oscillation death in a ring of coupled nonidentical oscillators is studied. We find that the rearrangement of the spatial frequencies may deform the domain of oscillation death and give rise to a ragged oscillation death in some parameter spaces. The usual critical curves with shape V in the parameter space of frequency-mismatch vs coupling-strength may become the shape W (or even shape WV). This phenomenon has been not only numerically observed in coupled nonidentical nonlinear systems, but also well supported by our theoretical analysis.     

FINITE LAYER ANALYSIS FOR SEMI-INFINITE SOILS (Ⅰ)——GENERAL THEORY

In the present paper a finite layer method is studied for the elastodynamics of transverse isotropic bodies. With this method, semi-infinite soils can be considered as an transverse isotropic half-space, its material functions varying with depth. Dividing the half-space into a series of layers in the direction of depth, the material functions in each layer are simulated by exponential functions. Consequently, the fundamental equations to be solved can be simplified if the Fourier transform with repsect to coordinates is used. We have obtained the relationship between the “layer forces” and “layer displacements”. This finite layer method, in fact, can also be called a semi-analytical method. It possesses those advantages as the usual semi-analytical methods do, and can be used to analyse the problem of the interaction between soils and structures. This paper is based on a portion of the author's dissertation submitted in partial fulfillment of the requirements of degree of Ph. D. at the Shanghai Institute of Appl. Math. & Mech., Shanghai.     

Fabrication linalool-functionalized hollow mesoporous silica spheres nanoparticles for efficiently enhance bactericidal activity

To develop a novel food preservation technology for efficiently enhance bactericidal activity in a long term, hollow mesoporous silica spheres (HMSS) with regular nanostructures were applied to encapsulate natural organic antimicrobial agents. The chemical structures, morphologies and thermal stabilities of linalool, HMSS and linalool-functionalized hollow mesoporous silica spheres (L-HMSS) nanoparticles were evaluated by polarimeter, field emission scanning electron microscope (FE-SEM), transmission electron microscope (TEM), fourier transform infrared (FT-IR), thermal gravimetric analyzer (TGA), nitrogen adsorption-desorption, zeta potential and small angle X-ray diffraction (SXRD). The results show that the linalool was successfully introduced into the cavities of HMSS, and the inorganic host exhibited a high loading capacity of about 1500 mg/g. In addition, after 48 h of incubation, the minimum bactericidal concentrations (MBC) of L-HMSS against Escherichia coli (E. coli), Salmonella enterica (S. enterica) and Staphylococcus aureus (S. aureus), Listeria monocytogenes (L. monocytogenes) were decreased to be 4 (< 5) mg/mL and 8 (< 10) mg/mL, respectively. These results revealed linalool-functionalized hollow mesoporous spheres could efficiently improve the bactericidal activities of the organic component. Furthermore, SEM images clearly showed that L-HMSS indeed had an extremely inhibitory effect against gram-negative (E. coli) and gram-positive (S. aureus) by breaking the structure of the cell membrane. This research is of great significance in the application of linalool in nano-delivery system as well as food industry.     

Synthesis and electro-optical properties of self-doped ionic conjugated polymers: poly[2-ethynyl-N-(4-sulfobutyl)pyridinium betaine]

A noble self-dopable conjugated polybetaine, poly[2-ethynyl-N-(4-sulfobutyl)pyridinium betaine] (PESPB) was synthesized by the activated polymerization of 2-ethynylpyridine with 1,4-butanesultone without any additional initiator or catalyst. This polymerization proceeded at the condition of high temperature (130 °C). The polymer yield and inherent viscosity were 82% and 0.13 dl/g, respectively. The chemical structure of PESPB was identified by various instrumental methods to have a conjugated ionic polymer bearing the sulfobetaine moieties. This poly(sulfobetaine) was found to be more soluble in salt solution than in salt-free solution. The photoluminescence peak is located at 530 nm corresponding to the photon energy of 2.34 eV. The photoluminescence intensity was increased as the temperature is increased. At 1 kHz and room temperature, the dielectric constant and electrical conductivity of PESPB were 5.7 and 3.5 × 10⁻⁹ S/cm, respectively.     

一类多输出函数研究

本文研究和讨论了作为多输出函数的N级模2~M背包变换平衡特性,给出了N级模2~M平衡背包变换的结构、计数和函数性质,指出了N级模2~M平衡背包变换本身作为密码变换函数存在着除了第M路外,所有各路的输出函数都是不完全函数的弱点,从而得出了背包变换是密码学弱函数的结论.     

DNS and LES of turbulent flow in a closed channel featuring a pattern of hemispherical roughness elements

Direct Numerical Simulations (DNS) and Large Eddy Simulations (LES) were performed for fully-developed turbulent flow in channels with smooth walls and walls featuring hemispherical roughness elements at shear Reynolds numbers Re_τ = 180 and 400, with the goal of studying the effect of these roughness elements on the wall-layer structure and on the friction factor. The LES and DNS approaches were verified first by comparison with existing DNS databases for smooth walls. Then, a parametric study for the hemispherical roughness elements was conducted, including the effects of shear Reynolds number, normalized roughness height (k⁺ = 10–20) and relative roughness spacing (s⁺/k⁺ = 2–6). The sensitivity study also included the effect of distribution pattern (regular square lattice vs. random pattern) of the roughness elements on the walls. The hemispherical roughness elements generate turbulence, thus increasing the friction factor with respect to the smooth-wall case, and causing a downward shift in the mean velocity profiles. The simulations revealed that the friction factor decreases with increasing Reynolds number and roughness spacing, and increases strongly with increasing roughness height. The effect of random element distribution on friction factor and mean velocities is however weak. In all cases, there is a clear cut between the inner layer near the wall, which is affected by the presence of the roughness elements, and the outer layer, which remains relatively unaffected. The study reveals that the presence of roughness elements of this shape promotes locally the instantaneous flow motion in the lateral direction in the wall layer, causing a transfer of energy from the streamwise Reynolds stress to the lateral component. The study indicates also that the coherent structures developing in the wall layer are rather similar to the smooth case but are lifted up by almost a constant wall-unit shift y⁺ (∼10–15), which, interestingly, corresponds to the relative roughness k⁺ = 10.     

Intrinsic intermediate gap states of TiO2 materials and their roles in charge carrier kinetics

Titanium dioxide (TiO₂) is regarded as an important prototype photocatalytic material for several decades. The charge carrier kinetics determines the photocatalytic properties of TiO₂ materials; this is found to be greatly dependent on electronic structures. It has been revealed that the intrinsic intermediate gap states (intrinsic GSs) play a significant role in charge carrier kinetics that drive the photocatalytic processes of TiO₂ materials, which are not well summarized until now. Motivated by this thought, the purpose of this review focuses on physiochemical science of the intrinsic GSs of TiO₂ materials and their important role in charge carrier kinetics. We first give a summary on the chemical resources of the intrinsic GSs in TiO₂ and their physiochemical nature. Their general energy distribution, charge carrier population, and the associated thermodynamic properties are also elaborated from an overall viewpoint. We further carefully summarize and compare the experimental studies on the energy and the density distribution of the intrinsic GSs and discuss the associated chemical resources and charge carrier localizations. Trapping is the dominant function of intrinsic GSs in the charge carrier kinetics of TiO₂ materials. The significant effect of trapping on the transport, recombination, and interfacial transfer of charge carriers are also comprehensive summarized. Furthermore, the effects of charge carrier kinetics on photocatalytic performances are also discussed to some extents. Because of the importance of intrinsic GSs in modulating charge carrier kinetics, it is expected to increase the photocatalytic activity by engineering the intrinsic GSs, not only for TiO₂ materials, but also for the other semiconductor photocatalysts.     

W掺杂ZnO电子结构与光学性质第一性原理计算

采用了基于密度泛函理论(DFT)的第一性原理平面波超软赝势方法,计算本征ZnO和不同W掺杂浓度下W:ZnO体系的电子结构和光学性质.计算结果表明:W掺杂可以提高ZnO的载流子浓度,从而改善ZnO的导电性.掺杂后,吸收光谱发生红移现象,且光学性质变化集中在低能量区,而高能量区的光学性质没有太大变化,计算结果与相关实验结果相符合.最后,结合电子结构定性分析了光学性质的变化.